Thallium | |
Electrons per shell | 2,8,18,32,18,3 |
Electron Configuration | [Xe] 4f14 5d10 6s2 6p1 |
Ground state | 2°1/2 |
Atomic Volume | 17.2 cm3 mol-1 |
Electronegativity | 1.62 |
Magnetic ordering | No data |
Mass magnetic susceptibility | -3 x 10-9 |
Molar magnetic susceptibility | -6.13 x 10-10 |
Speed of sound | 818 m s-1 |
Thermal Properties | |
Enthalpy of Atomization | 179.9 kJ mol-1 @25°C |
Enthalpy of Fusion | 4.31 kJ mol-1 |
Enthalpy of Vaporisation | 166.1 kJ mol-1 |
Heat Capacity | 26.32 J mol-1 K-1 |
Thermal Conductivity | 46.1 W m-1 K-1 |
Thermal Expansion | 29.9 μm m-1 K-1 |
Hardness | |
Brinell hardness | 26.4 MPa |
Mohs hardness | 1.2 |
Elastic Properties | |
Bulk modulus | 43 GPa |
Poisson ratio | 0.45 |
Shear modulus | 2.8 GPa |
Young's modulus | 8 GPa |
Electrical Properties | |
Electrical resistivity | 1.5 x 10-7 Ω m |
Electrical conductivity | 0.0617 106/cm Ω |
Chemical Properties | |
Electrochemical Equivalent | 7.625 g Ah-1 |
Electron Work Function | 3.84 eV |
Valence Electron Potential (-eV) | 9.6 |
Ionization Potential | |
First | 6.108 |
Second | 20.428 |
Third | 29.829 |
Energy Levels | |
Kα1 (intensity 100) | 72.8715 KeV |
Kα2 (intensity 50) | 70.8319 KeV |
Kβ1 (intensity 0) | 82.576 KeV |
Lα1 (intensity 100) | 10.2685 KeV |
Lα2 (intensity 10) | 10.1728 KeV |
Lβ1 (intensity 36) | 12.2133 KeV |
Lβ2 (intensity 20) | 12.2715 KeV |
Lβ3 (intensity 6.3) | 12.3875 KeV |
Lβ4 (intensity 4) | 11.9297 KeV |
Lγ1 (intensity 6) | 14.2915 KeV |
Lγ2 (intensity 2.7) | 14.62 KeV |
Lγ3 (intensity 2) | 10.99 KeV |
Ll (intensity 4.5) | 8.9523 KeV |
Atomic Radii | |
Empirical | 190 pm |
Bohr Radius | 156 pm |
Covalent Radius | 148 pm |
Van der Waals | 196 pm |
Triple covalent | 150 pm |
Metallic | 170 pm |
Oxidation States | |
Main | Tl+1 |
Other | Tl+3 |
Ionisation Energies (kJ mol-1) | |
M - M+ | 589.3 |
M+ - M2+ | 1971 |
M2+ - M3+ | 2878 |
M3+ - M4+ | 4900 |
M4+ - M5+ | 6100 |
M5+ - M6+ | 8300 |
M6+ - M7+ | 9500 |
M7+ - M8+ | 11300 |
M8+ - M9+ | 1400 |
M9+ - M10+ | 16000 |
Covalent Bonds (kJ mol-1) | |
Tl+1-H | 185 |
Tl+3-C | 125 |
Tl+3-O | 375 |
Tl+3-F | 460 |
Tl+3-Cl | 368 |
Tl-Tl | 63 |
Vapour Pressure | ||||||
P (Pa) | 1 | 10 | 100 | 1K | 10K | 100K |
T (K) | 882 | 977 | 1097 | 1252 | 1461 | 1758 |
Crystal Structure | |
Structure | Hexagonal close packed |
a = 345.66 pm | |
b = 345.66 pm | |
c = 552.48 pm | |
α = 90° | |
β = 90° | |
γ = 120° |